Add documentation for xmllint --xpath

https://bugzilla.gnome.org/show_bug.cgi?id=694822

this wasn't documented in the man page, and there was a typo in
xmllint help output.
diff --git a/doc/xmllint.xml b/doc/xmllint.xml
index 9a41b4e..5f0f000 100644
--- a/doc/xmllint.xml
+++ b/doc/xmllint.xml
@@ -69,6 +69,7 @@
 			<arg choice="plain"><option>--version</option></arg>
 			<arg choice="plain"><option>--debug</option></arg>
 			<arg choice="plain"><option>--shell</option></arg>
+			<arg choice="plain"><option>--xpath "<replaceable class="option">XPath_expression</replaceable>"</option></arg>
 			<arg choice="plain"><option>--debugent</option></arg>
 			<arg choice="plain"><option>--copy</option></arg>
 			<arg choice="plain"><option>--recover</option></arg>
@@ -528,6 +529,19 @@
 		</varlistentry>
 
 		<varlistentry>
+	<term><option>--xpath "<replaceable class="option">XPath_expression</replaceable>"</option></term>
+	<listitem>
+		<para>
+			Run an XPath expression given as argument and print the
+			result. In case of a nodeset result, each node in the
+			node set is serialized in full in the output. In case
+			of an empty node set the "XPath set is empty" result
+			will be shown and an error exit code will be returned.
+		</para>
+	</listitem>
+		</varlistentry>
+
+		<varlistentry>
 	<term><option>--stream</option></term>
 	<listitem>
 		<para>