Fixes Issue #16114: The subprocess module no longer provides a
misleading error message stating that args[0] did not exist when
either the cwd or executable keyword arguments specified a path that
did not exist.

It now keeps track of if the child got as far as preexec and reports it if
not back to the parent via a special "noexec" error message value in
the error pipe so that the cwd can be blamed for a failed chdir
instead of the exec of the executable being blamed instead.

The executable is also always reported accurately when exec fails.

Unittests enhanced to cover these cases.
diff --git a/Modules/_posixsubprocess.c b/Modules/_posixsubprocess.c
index 59673f4..19ca31f 100644
--- a/Modules/_posixsubprocess.c
+++ b/Modules/_posixsubprocess.c
@@ -354,7 +354,7 @@
            PyObject *preexec_fn,
            PyObject *preexec_fn_args_tuple)
 {
-    int i, saved_errno, unused;
+    int i, saved_errno, unused, reached_preexec = 0;
     PyObject *result;
     const char* err_msg = "";
     /* Buffer large enough to hold a hex integer.  We can't malloc. */
@@ -438,6 +438,7 @@
         POSIX_CALL(setsid());
 #endif
 
+    reached_preexec = 1;
     if (preexec_fn != Py_None && preexec_fn_args_tuple) {
         /* This is where the user has asked us to deadlock their program. */
         result = PyObject_Call(preexec_fn, preexec_fn_args_tuple, NULL);
@@ -487,6 +488,10 @@
         }
         unused = write(errpipe_write, cur, hex_errno + sizeof(hex_errno) - cur);
         unused = write(errpipe_write, ":", 1);
+        if (!reached_preexec) {
+            /* Indicate to the parent that the error happened before exec(). */
+            unused = write(errpipe_write, "noexec", 6);
+        }
         /* We can't call strerror(saved_errno).  It is not async signal safe.
          * The parent process will look the error message up. */
     } else {