bpo-41900: C14N 2.0 serialisation failed for unprefixed attributes when a default namespace was defined. (GH-22474)

diff --git a/Lib/xml/etree/ElementTree.py b/Lib/xml/etree/ElementTree.py
index da2bcad..7a26900 100644
--- a/Lib/xml/etree/ElementTree.py
+++ b/Lib/xml/etree/ElementTree.py
@@ -1876,6 +1876,11 @@
                 self._declared_ns_stack[-1].append((uri, prefix))
                 return f'{prefix}:{tag}' if prefix else tag, tag, uri
 
+        if not uri:
+            # As soon as a default namespace is defined,
+            # anything that has no namespace (and thus, no prefix) goes there.
+            return tag, tag, uri
+
         raise ValueError(f'Namespace "{uri}" is not declared in scope')
 
     def data(self, data):