diff --git a/docs/development/test-vectors.rst b/docs/development/test-vectors.rst
index dc89caf..59dfdf9 100644
--- a/docs/development/test-vectors.rst
+++ b/docs/development/test-vectors.rst
@@ -440,6 +440,7 @@
 * CAST5 (ECB) from :rfc:`2144`.
 * CAST5 (CBC, CFB, OFB) generated by this project.
   See: :doc:`/development/custom-vectors/cast5`
+* ChaCha20 from :rfc:`7539`.
 * ChaCha20Poly1305 from :rfc:`7539`, `OpenSSL's evpciph.txt`_, and the
   `BoringSSL ChaCha20Poly1305 tests`_.
 * IDEA (ECB) from the `NESSIE IDEA vectors`_ created by `NESSIE`_.
diff --git a/vectors/cryptography_vectors/ciphers/ChaCha20/rfc7539.txt b/vectors/cryptography_vectors/ciphers/ChaCha20/rfc7539.txt
new file mode 100644
index 0000000..c1541cf
--- /dev/null
+++ b/vectors/cryptography_vectors/ciphers/ChaCha20/rfc7539.txt
@@ -0,0 +1,23 @@
+# The vectors are from RFC 7539 Appendix A.2. They are reformatted into NIST
+# form for our vector loaders.
+
+COUNT = 0
+KEY = 0000000000000000000000000000000000000000000000000000000000000000
+NONCE = 000000000000000000000000
+INITIAL_BLOCK_COUNTER = 0
+PLAINTEXT = 00000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
+CIPHERTEXT = 76b8e0ada0f13d90405d6ae55386bd28bdd219b8a08ded1aa836efcc8b770dc7da41597c5157488d7724e03fb8d84a376a43b8f41518a11cc387b669b2ee6586
+
+COUNT = 1
+KEY = 0000000000000000000000000000000000000000000000000000000000000001
+NONCE = 000000000000000000000002
+INITIAL_BLOCK_COUNTER = 1
+PLAINTEXT = 416e79207375626d697373696f6e20746f20746865204945544620696e74656e6465642062792074686520436f6e7472696275746f7220666f72207075626c69636174696f6e20617320616c6c206f722070617274206f6620616e204945544620496e7465726e65742d4472616674206f722052464320616e6420616e792073746174656d656e74206d6164652077697468696e2074686520636f6e74657874206f6620616e204945544620616374697669747920697320636f6e7369646572656420616e20224945544620436f6e747269627574696f6e222e20537563682073746174656d656e747320696e636c756465206f72616c2073746174656d656e747320696e20494554462073657373696f6e732c2061732077656c6c206173207772697474656e20616e6420656c656374726f6e696320636f6d6d756e69636174696f6e73206d61646520617420616e792074696d65206f7220706c6163652c207768696368206172652061646472657373656420746f
+CIPHERTEXT = 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
+
+COUNT = 2
+KEY = 1c9240a5eb55d38af333888604f6b5f0473917c1402b80099dca5cbc207075c0
+NONCE = 000000000000000000000002
+INITIAL_BLOCK_COUNTER = 42
+PLAINTEXT = 2754776173206272696c6c69672c20616e642074686520736c6974687920746f7665730a446964206779726520616e642067696d626c6520696e2074686520776162653a0a416c6c206d696d737920776572652074686520626f726f676f7665732c0a416e6420746865206d6f6d65207261746873206f757467726162652e
+CIPHERTEXT = 62e6347f95ed87a45ffae7426f27a1df5fb69110044c0d73118effa95b01e5cf166d3df2d721caf9b21e5fb14c616871fd84c54f9d65b283196c7fe4f60553ebf39c6402c42234e32a356b3e764312a61a5532055716ead6962568f87d3f3f7704c6a8d1bcd1bf4d50d6154b6da731b187b58dfd728afa36757a797ac188d1